Reaction
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Xantphos Pd G3

Reaction
Product Name
Xantphos Pd G3
CAS No.
1445085-97-1
Chemical Name
Xantphos Pd G3
Synonyms
XantPhos Pd G3;Pd Catalysts XantPhos-Pd-G3;Xantphos Palladacycle Gen. 3;XantPhos Pd G3[XantPhos Pd G3;Xantphos Palladacycle Gen. 3 ISO 9001：2015 REACH;Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xant...;Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(I;Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladium(II);Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II);methanesulfonato[9,9-dime-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphen]pd(ii) ch2cl2 adduct
CBNumber
CB62709871
Molecular Formula
C52H46NO4P2PdS-
Formula Weight
949.358462
MOL File
1445085-97-1.mol
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Xantphos Pd G3 Property

Melting point:
164-167 °C (decomposition)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
Powder
color 
pale yellow
InChI
InChI=1S/C39H32OP2.C12H10N.CH4O3S.Pd/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h3-28H,1-2H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;-1;;
InChIKey
JIMOHYWEUIAPAA-UHFFFAOYSA-N
SMILES
[Pd].S(C([H])([H])[H])(=O)(=O)O[H].P(C1C([H])=C([H])C([H])=C([H])C=1[H])(C1C([H])=C([H])C([H])=C([H])C=1[H])C1=C([H])C([H])=C([H])C2=C1OC1C(=C([H])C([H])=C([H])C=1C2(C([H])([H])[H])C([H])([H])[H])P(C1C([H])=C([H])C([H])=C([H])C=1[H])C1C([H])=C([H])C([H])=C([H])C=1[H].N([H])([H])C1=C([H])C([H])=C([H])C([H])=C1C1=C([H])C([H])=C([H])C([H])=[C-]1
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
763039
Product name
XantPhos Pd G3
Purity
95%
Packaging
250MG
Price
$54.2
Updated
2023/06/20
Sigma-Aldrich
Product number
763039
Product name
XantPhos Pd G3
Purity
95%
Packaging
1G
Price
$164
Updated
2023/06/20
Sigma-Aldrich
Product number
932213
Product name
XantPhos Pd G3 ChemBeads
Packaging
1G
Price
$276
Updated
2023/06/20
Sigma-Aldrich
Product number
763039
Product name
XantPhos Pd G3
Purity
95%
Packaging
5G
Price
$678
Updated
2023/06/20
Strem Chemicals
Product number
46-0957
Product name
Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II) dichloromethane adduct, min. 98% [Xantphos Palladacycle Gen. 3]
Packaging
500mg
Price
$85
Updated
2024/03/01
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Xantphos Pd G3 Chemical Properties,Usage,Production

Reaction

  1. Catalyst for the Negishi coupling of aryl halides and alkylzinc reagents.
  2. Catalyst for the synthesis of tetraacetylated p-tolyl thioglucose.
  3. Cooperative catalyst for the direct asymmetric α-allylation of acyclic esters.

Uses

Xantphos Pd G3 is used as a catalyst in many reactions. It is a third generation (G3) Buchwald precatalyst. XantPhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions.

General Description

XantPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. XantPhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

Xantphos Pd G3 Preparation Products And Raw materials

Raw materials

Preparation Products

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Xantphos Pd G3 Suppliers

China 97 India 1 United States 8 Global 106
Alfa Chemistry
Tel
1-516-6625404
Fax
1-516-927-0118
Email
support@alfa-chemistry.com
Country
United States
ProdList
9171
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60
Alfa Chemistry
Tel
+1-5166625404
Fax
1-516-927-0118
Email
Info@alfa-chemistry.com
Country
United States
ProdList
21317
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58
Accela ChemBio Inc.
Tel
(+1)-858-699-3322
Fax
(+1)-858-876-1948
Email
info@accelachem.com
Country
United States
ProdList
19965
Advantage
58
Protheragen-ING
Tel
+16313385890
Email
info@protheragen-ing.com
Country
United States
ProdList
1091
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58
Aladdin Scientific
Tel
+1-833-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
52927
Advantage
58
Aladdin Scientific
Tel
+1-833-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57511
Advantage
58
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View Lastest Price from Xantphos Pd G3 manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Xantphos Palladacycle Gen. 3 1445085-97-1
Price
US $0.00/KG
Min. Order
25KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-29
Hebei Guanlang Biotechnology Co,.LTD
Product
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 1445085-97-1
Price
US $8.70/g
Min. Order
10g
Purity
99%
Supply Ability
10000kg
Release date
2021-07-16
Wuhan LPBchem Technology Co.,Ltd
Product
Xantphos Pd G3 1445085-97-1
Price
US $10.00-10.00/g
Min. Order
1g
Purity
0.98
Supply Ability
50kg
Release date
2020-12-01

1445085-97-1, Xantphos Pd G3Related Search:

XantPhos-Pd-G2 tBuXPhos-Pd-G3 XantPhos Pd G4 XPhos Pd G3 SPhos Palladacycle Gen. 4 XPhos Pd G4 BrettPhos Pd G3 XPhos Pd G2 RuPhos Pd G1 Methyl t--Butyl Ether Adduct SPhos Pd G2 BrettPhosPalladacycle Palladacycle Gen. 3 t-BuXphos Palladacycle Gen. 4 RuPhos Palladacycle Gen. 4 t-BuBrettPhos Palladacycle Gen. 3 SPhos Pd G3 SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2

  • Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladiuM(II) dichloroMethane adduct, Min. 98%
  • Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladium(II)
  • Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(I
  • METHANESULFONATO[9,9-DIMETHYL-4,5-BIS(DIPHENYLPHOSPHINO)XANTHENE][2'-AMINO-1,1'-BIPHENYL]PALLADIUM(II)DICHLOROMETHANEADDUCT,MIN.98%[XANTPHOSPALLADACYCLEGEN.3]
  • Xantphos Palladacycle Gen. 3
  • Methanesulfonato[4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene](2-amino-1,1-biphenyl-2-yl)palladium(II)
  • Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II) dichloromethane adduct,[Xantphos Palladacycle Gen. 3]
  • Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladiuM(II) dichloroMethane adduct
  • 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene][2’-amino-2-biphenylyl][(methylsulfonyl)oxy]palladium(II)
  • methanesulfonato[9,9-dime-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphen]pd(ii) ch2cl2 adduct
  • Xantphos Palladacycle Gen. 3 ISO 9001：2015 REACH
  • Pd Catalysts XantPhos-Pd-G3
  • Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xant...
  • Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene](2'-amino-1,1'-biphenyl-2-yl)palladium(II) (Xantphos Pd G3)
  • [(4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate/XantPhosPdG3
  • XantPhos Pd G3[XantPhos Pd G3
  • 2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][[5-(diphenylphosphino)-9,9-dimethyl-9H-xanthen-4-yl]diphenylphosphine-κP](methanesulfonato-κO)palladium
  • XantPhos Pd G3
  • Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II)
  • 2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][[5-(diphenylphosphino)-9,9-dimethyl-9H-xanthen-4-yl]diphenylphosphine-κP](methanesulfonato-κO)palladium
  • Methanesulfonato [(R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene] (2'-amino-1,1'-biphenyl-2-yl)palladium(II)，R-Binap Pd G3
  • Methanesulfonato[4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene](2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • 1445085-97-1
  • C52H45NO4P2PdS
  • C39H32OP2C13H13NO3PdS
  • Buchwald Ligands&Precatalysts
  • Buchwald Precatalysts Series
  • Pd